{"id":619,"date":"2016-01-28T10:34:22","date_gmt":"2016-01-28T01:34:22","guid":{"rendered":"https:\/\/labs.eng.hokudai.ac.jp\/labo\/orgsynth\/?page_id=619"},"modified":"2020-06-24T11:57:49","modified_gmt":"2020-06-24T02:57:49","slug":"asymmetric-isomerization","status":"publish","type":"page","link":"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/research\/asymmetric-isomerization","title":{"rendered":"\u4e0d\u6589\u7570\u6027\u5316\u53cd\u5fdc"},"content":{"rendered":"<h1>\u30a2\u30ea\u30eb\u30a2\u30eb\u30b3\u30fc\u30eb\u985e\u306e\u4e0d\u6589\u7570\u6027\u5316\u53cd\u5fdc<\/h1>\n<p>\u30a2\u30ea\u30eb\u30a2\u30eb\u30b3\u30fc\u30eb\u306f\u6709\u6a5f\u5408\u6210\u5316\u5b66\u53cd\u5fdc\u3067\u983b\u7e41\u306b\u767b\u5834\u3059\u308b\u30e1\u30b8\u30e3\u30fc\u306a\u5316\u5408\u7269\u7fa4\u306e\u4e00\u3064\u3067\u3059\u3002\u56f3\uff14-\uff11\u306b\u793a\u3059\u3088\u3046\u306b\u3001\u6700\u8fd1\u3001\u308f\u305f\u3057\u305f\u3061\u306f\u5149\u5b66\u6d3b\u6027\u30b8\u30db\u30b9\u30d5\u30a3\u30f3TolBINAP\u3068\u30b8\u30a2\u30df\u30f3DBAPEN\u3092\u914d\u4f4d\u5b50\u3068\u3059\u308b\u30eb\u30c6\u30cb\u30a6\u30e0\u932f\u4f53\u3068\u6c34\u9178\u5316\u30ab\u30ea\u30a6\u30e0\u304b\u3089\u6210\u308b\u89e6\u5a92\u3092\u7528\u3044\u308b\u3053\u3068\u3067\u3001\u30a2\u30ea\u30eb\u30a2\u30eb\u30b3\u30fc\u30eb\u304b\u3089\u5149\u5b66\u7684\u306b\u307b\u307c\u7d14\u7c8b\u306a\uf062\u7f6e\u63db\u30a2\u30eb\u30c7\u30d2\u30c9\u3092\u5408\u6210\u3059\u308b\u3053\u3068\u306b\u6210\u529f\u3057\u307e\u3057\u305f<sup>[D1]<\/sup>\u3002\u3053\u306e\u53cd\u5fdc\u306f\u3001\u30a2\u30ea\u30eb\u30a2\u30eb\u30b3\u30fc\u30eb\u306e\uf061\u4f4d\u6c34\u7d20\u3092\u30a8\u30ca\u30f3\u30c1\u30aa\u9762\u9078\u629e\u7684\u306b\uf067\u4f4d\u306b\u79fb\u52d5\u3059\u308b\u6975\u3081\u3066\u52b9\u7387\u7684\u306a\u5909\u63db\u3067\u3059\u3002\u5b8c\u74a7\u306a\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u6027\u306b\u52a0\u3048\u30011000\u5206\u306e1\u5f53\u91cf\u306e\u89e6\u5a92\u3067\u53cd\u5fdc\u304c\u9032\u884c\u3059\u308b\u9ad8\u53cd\u5fdc\u6027\u306e\u305f\u3081\u3001\u4e16\u754c\u7684\u306b\u6ce8\u76ee\u3055\u308c\u3066\u3044\u307e\u3059\u3002\u4ee3\u8868\u7684\u306a\u56fd\u969b\u7684\u5316\u5b66\u96d1\u8a8cAngew. Chem. Int. Ed.\u306eVery Important Paper (VIP: \u30c8\u30c3\u30d75%\u4ee5\u5185\u306e\u8a55\u4fa1)\u306b\u9078\u5b9a\u3055\u308c\u3001\u7814\u7a76\u5185\u5bb9\u304c\u5185\u8868\u7d19\u306b\u30cf\u30a4\u30e9\u30a4\u30c8\u3055\u308c\u307e\u3057\u305f\u3002<\/p>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter size-full wp-image-513\" src=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/beb696158d384441ea46728c4350ba69.png\" alt=\"\u30b9\u30e9\u30a4\u30c923\" width=\"720\" height=\"540\" srcset=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/beb696158d384441ea46728c4350ba69.png 720w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/beb696158d384441ea46728c4350ba69-300x225.png 300w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/beb696158d384441ea46728c4350ba69-230x173.png 230w\" sizes=\"(max-width: 720px) 100vw, 720px\" \/><\/p>\n<p>\u3053\u306e\u89e6\u5a92\u306f\u3001\u591a\u69d8\u306a\u7f6e\u63db\u69d8\u5f0f\u3092\u3082\u3064\u30a2\u30ea\u30eb\u30a2\u30eb\u30b3\u30fc\u30eb\u306e\u4e0d\u6589\u7570\u6027\u5316\u306b\u9069\u7528\u3067\u304d\u307e\u3059<sup>[D1]<\/sup>\u3002\u4f8b\u3048\u3070\u3001\u56f3\uff14-\uff12\u306b\u793a\u3059\u3088\u3046\u306b\u3001\u5165\u624b\u5bb9\u6613\u306a\u30cd\u30ed\u30fc\u30eb\u304b\u3089\u5bfe\u5fdc\u3059\u308b\uf067\u7f6e\u63db\u30a2\u30eb\u30c7\u30d2\u30c9\u3092&gt;99% ee\u3067\u5408\u6210\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002\u3053\u306e\u30a2\u30eb\u30c7\u30d2\u30c9\u306f\u9700\u8981\u306e\u6975\u3081\u3066\u591a\u3044\u9999\u6599\u30e1\u30f3\u30c8\u30fc\u30eb\u306e\u5408\u6210\u539f\u6599\u3067\u3042\u308a\u3001\u5316\u5b66\u7cfb\u4f01\u696d\u3068\u5354\u529b\u3057\u3066\u5b9f\u7528\u5316\u691c\u8a0e\u3092\u884c\u3063\u3066\u3044\u307e\u3059\u3002<\/p>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter size-full wp-image-514\" src=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/ce41a13b6a14932bef6aacec3bcf4529.png\" alt=\"\u30b9\u30e9\u30a4\u30c924\" width=\"720\" height=\"540\" srcset=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/ce41a13b6a14932bef6aacec3bcf4529.png 720w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/ce41a13b6a14932bef6aacec3bcf4529-300x225.png 300w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/ce41a13b6a14932bef6aacec3bcf4529-230x173.png 230w\" sizes=\"(max-width: 720px) 100vw, 720px\" \/><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u30a2\u30ea\u30eb\u30a2\u30eb\u30b3\u30fc\u30eb\u985e\u306e\u4e0d\u6589\u7570\u6027\u5316\u53cd\u5fdc \u30a2\u30ea\u30eb\u30a2\u30eb\u30b3\u30fc\u30eb\u306f\u6709\u6a5f\u5408\u6210\u5316\u5b66\u53cd\u5fdc\u3067\u983b\u7e41\u306b\u767b\u5834\u3059\u308b\u30e1\u30b8\u30e3\u30fc\u306a\u5316\u5408\u7269\u7fa4\u306e\u4e00\u3064\u3067\u3059\u3002\u56f3\uff14-\uff11\u306b\u793a\u3059\u3088\u3046\u306b\u3001\u6700\u8fd1\u3001\u308f\u305f\u3057\u305f\u3061\u306f\u5149\u5b66\u6d3b\u6027\u30b8\u30db\u30b9\u30d5\u30a3\u30f3TolBINAP\u3068\u30b8\u30a2\u30df\u30f3DBAPEN\u3092\u914d\u4f4d [&hellip;]<\/p>\n","protected":false},"author":2,"featured_media":0,"parent":21,"menu_order":20,"comment_status":"closed","ping_status":"closed","template":"","meta":[],"_links":{"self":[{"href":"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-json\/wp\/v2\/pages\/619"}],"collection":[{"href":"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-json\/wp\/v2\/comments?post=619"}],"version-history":[{"count":1,"href":"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-json\/wp\/v2\/pages\/619\/revisions"}],"predecessor-version":[{"id":2318,"href":"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-json\/wp\/v2\/pages\/619\/revisions\/2318"}],"up":[{"embeddable":true,"href":"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-json\/wp\/v2\/pages\/21"}],"wp:attachment":[{"href":"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-json\/wp\/v2\/media?parent=619"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}