{"id":323,"date":"2016-01-14T11:57:54","date_gmt":"2016-01-14T02:57:54","guid":{"rendered":"https:\/\/labs.eng.hokudai.ac.jp\/labo\/orgsynth\/?page_id=323"},"modified":"2020-06-24T11:56:56","modified_gmt":"2020-06-24T02:56:56","slug":"ketones","status":"publish","type":"page","link":"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/research\/ketones","title":{"rendered":"\u30b1\u30c8\u30f3\u985e\u306e\u4e0d\u6589\u6c34\u7d20\u5316\u53cd\u5fdc"},"content":{"rendered":"<p>\u308f\u305f\u3057\u305f\u3061\u306f\u3001\u533b\u85ac\u3084\u9999\u6599\u306a\u3069\u306e\u539f\u6599\u3068\u3057\u3066\u9700\u8981\u304c\u975e\u5e38\u306b\u591a\u3044\u300c\u5149\u5b66\u6d3b\u6027\u30a2\u30eb\u30b3\u30fc\u30eb\u985e\u300d\u306e\u4f5c\u308a\u5206\u3051\u306b\u7740\u76ee\u3057\u3066\u7814\u7a76\u3092\u9032\u3081\u3066\u304d\u307e\u3057\u305f\u3002\u5149\u5b66\u6d3b\u6027\u3068\u306f\u3001\u3042\u308b\u5206\u5b50\u7fa4\u304c\u53f3\u624b\u578b\u3042\u308b\u3044\u306f\u5de6\u624b\u578b\u306e\u3069\u3061\u3089\u304b\u4e00\u65b9\u3060\u3051\u3067\u3042\u308b\u72b6\u614b\u3092\u793a\u3057\u307e\u3059\u3002\u30a2\u30eb\u30b3\u30fc\u30eb\u306e\u5408\u6210\u306b\u306f\u3044\u308d\u3044\u308d\u306a\u5408\u6210\u6cd5\u304c\u8003\u3048\u3089\u308c\u307e\u3059\u304c\u3001\u308f\u305f\u3057\u305f\u3061\u304c\u9078\u3093\u3060\u306e\u306f\u3001\u300c\u30b1\u30c8\u30f3\u985e\u306e\u4e0d\u6589\u6c34\u7d20\u5316\u53cd\u5fdc\u300d\u3067\u3059\u3002\u56f3\uff12-\uff11\u306b\u305d\u306e\u6982\u8981\u3092\u793a\u3057\u307e\u3059\u3002\u30b1\u30c8\u30f3\u3068\u3088\u3070\u308c\u308b\u5e73\u9762\u6027\u5206\u5b50\u306e\u8868\u307e\u305f\u306f\u88cf\u304b\u3089\u9078\u629e\u7684\u306b\u6c34\u7d20\u3092\u4ed8\u52a0\u3055\u305b\u308b\u3053\u3068\u3067\u3001\u5149\u5b66\u6d3b\u6027\u30a2\u30eb\u30b3\u30fc\u30eb\u3092\u4f5c\u308a\u5206\u3051\u308b\u3001\u3059\u306a\u308f\u3061\u3001\u7acb\u4f53\u9078\u629e\u7684\uff08\u3053\u306e\u5834\u5408\u306f\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u7684\uff09\u306b\u5408\u6210\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002\u305f\u3060\u3057\u3001\u5b89\u5b9a\u306a\u5206\u5b50\u3067\u3042\u308b\u30b1\u30c8\u30f3\u3068\u6c34\u7d20\u3092\u305f\u3060\u6df7\u305c\u305f\u3060\u3051\u3067\u306f\u53cd\u5fdc\u3057\u307e\u305b\u3093\u3002\u305d\u3053\u3067\u3001\u308f\u305f\u3057\u305f\u3061\u306f\u3001\u30b1\u30c8\u30f3\u306e\u6c34\u7d20\u5316\u3092\u52b9\u7387\u7684\u306b\u30b5\u30dd\u30fc\u30c8\u3059\u308b\u5149\u5b66\u6d3b\u6027\u306a\u300c\u5206\u5b50\u89e6\u5a92\u300d\u3092\u4f7f\u3046\u3053\u3068\u306b\u3057\u307e\u3057\u305f\u3002\u512a\u308c\u305f\u5206\u5b50\u89e6\u5a92\u306f\u6d3b\u6027\u304c\u9ad8\u304f\u3001\u89e6\u5a921\u5206\u5b50\u306710\u4e07\u5206\u5b50\u3082\u306e\u30a2\u30eb\u30b3\u30fc\u30eb\u3092\u5408\u6210\u3067\u304d\u3001\u7d4c\u6e08\u6027\u306b\u3068\u3066\u3082\u512a\u308c\u3066\u3044\u307e\u3059<sup>[B1]<\/sup>\u3002\u3053\u308c\u307e\u3067\u306b\u308f\u305f\u3057\u305f\u3061\u306f\u3001\u89e6\u5a92\uff11\u5206\u5b50\u3067240\u4e07\u5206\u5b50\u3082\u306e\u5149\u5b66\u6d3b\u6027\u30a2\u30eb\u30b3\u30fc\u30eb\u3092\u4f5c\u308a\u51fa\u3059\u3053\u3068\u306e\u3067\u304d\u308b\u89e6\u5a92\u3082\u958b\u767a\u3057\u3066\u304a\u308a\u3001\u30ad\u30ed\u30b0\u30e9\u30e0\u5358\u4f4d\u3067\u76ee\u7684\u7269\u3092\u5f97\u308b\u3053\u3068\u306b\u3082\u6210\u529f\u3057\u3066\u3044\u307e\u3059 <sup>[B2]<\/sup>\u3002\u307e\u305f\u3001\u3053\u306e\u53cd\u5fdc\u306f\u30b1\u30c8\u30f3\u306b\u6c34\u7d20\u3092\u4ed8\u52a0\u3055\u305b\u308b\u3060\u3051\u3067\u3001\u526f\u751f\u6210\u7269\u3092\u51fa\u3059\u3053\u3068\u306a\u304f\u5149\u5b66\u6d3b\u6027\u30a2\u30eb\u30b3\u30fc\u30eb\u3092\u975e\u5e38\u306b\u9ad8\u3044\u7acb\u4f53\u9078\u629e\u6027\u3067\u4e0e\u3048\u3001\u74b0\u5883\u306b\u3082\u512a\u3057\u3044\u53cd\u5fdc\u3067\u3059\u3002\uff08\u53f3\u624b\u578b\u3068\u5de6\u624b\u578b\u5206\u5b50\u306e\u30e2\u30eb\u6bd4\u304c&gt;99.5 : 0.5\u306e\u3068\u304d\u3001&gt;99% ee\u3068\u8868\u3057\u307e\u3059\u3002\uff09\u3057\u305f\u304c\u3063\u3066\u3001\u30b1\u30c8\u30f3\u985e\u306e\u4e0d\u6589\u6c34\u7d20\u5316\u306f\u3001\u74b0\u5883\u8abf\u548c\u3092\u3082\u898b\u636e\u3048\u305f\u7406\u60f3\u7684\u306a\u5408\u6210\u30d7\u30ed\u30bb\u30b9\u3068\u306a\u308a\u5f97\u308b\u306e\u3067\u3059\u3002<\/p>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter wp-image-491 size-full\" src=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/6f89200a233102a09ad3b260eee61445.png\" alt=\"\u30b9\u30e9\u30a4\u30c903\" width=\"720\" height=\"540\" srcset=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/6f89200a233102a09ad3b260eee61445.png 720w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/6f89200a233102a09ad3b260eee61445-300x225.png 300w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/6f89200a233102a09ad3b260eee61445-230x173.png 230w\" sizes=\"(max-width: 720px) 100vw, 720px\" 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decoding=\"async\" loading=\"lazy\" class=\"aligncenter size-full wp-image-492\" src=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/e19a3fc06b040784e999b95d2f032e0b.png\" alt=\"\u30b9\u30e9\u30a4\u30c904\" width=\"720\" height=\"540\" srcset=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/e19a3fc06b040784e999b95d2f032e0b.png 720w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/e19a3fc06b040784e999b95d2f032e0b-300x225.png 300w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/e19a3fc06b040784e999b95d2f032e0b-230x173.png 230w\" sizes=\"(max-width: 720px) 100vw, 720px\" 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class=\"aligncenter size-full wp-image-493\" src=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/1dc4d19d2886d8dd5d75a53eed27a1bc.png\" alt=\"\u30b9\u30e9\u30a4\u30c905\" width=\"720\" height=\"540\" srcset=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/1dc4d19d2886d8dd5d75a53eed27a1bc.png 720w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/1dc4d19d2886d8dd5d75a53eed27a1bc-300x225.png 300w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/1dc4d19d2886d8dd5d75a53eed27a1bc-230x173.png 230w\" sizes=\"(max-width: 720px) 100vw, 720px\" \/><\/p>\n<p>\u3053\u306e\u89e6\u5a92\u306f\u3001\u5e83\u7bc4\u56f2\u306e\u30b1\u30c8\u30f3\u985e\u306e\u4e0d\u6589\u6c34\u7d20\u5316\u53cd\u5fdc\u306b\u5bfe\u3057\u3066\u9069\u7528\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002\u56f3\uff12-\uff14\u306b\u5408\u6210\u3067\u304d\u308b\u5149\u5b66\u6d3b\u6027\u306e\u30a2\u30eb\u30b3\u30fc\u30eb\u4f8b\u3092\u793a\u3057\u307e\u3059<sup>[B1,B3]<\/sup>\u3002\u5316\u5b66\u7cfb\u4f01\u696d\u3068\u306e\u5171\u540c\u7814\u7a76\u306b\u3088\u308a\u3001\u89e6\u5a92\u306e\u8a66\u85ac\u8ca9\u58f2\u3084\u5149\u5b66\u6d3b\u6027\u30a2\u30eb\u30b3\u30fc\u30eb\u306e\u53d7\u8a17\u5408\u6210\u3092\u958b\u59cb\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3057\u305f\u3002<a href=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/2-3.pdf\" target=\"_blank\" rel=\"noopener noreferrer\">\uff08PDF\uff09<\/a><\/p>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter size-full wp-image-494\" src=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/6d3eceb04d96c11441a0f84b5d8cb6b0.png\" alt=\"\u30b9\u30e9\u30a4\u30c906\" width=\"720\" height=\"540\" srcset=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/6d3eceb04d96c11441a0f84b5d8cb6b0.png 720w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/6d3eceb04d96c11441a0f84b5d8cb6b0-300x225.png 300w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/6d3eceb04d96c11441a0f84b5d8cb6b0-230x173.png 230w\" sizes=\"(max-width: 720px) 100vw, 720px\" \/><\/p>\n<p>\u5206\u5b50\u89e6\u5a92\u306e\u8a2d\u8a08\u3067\u306f\u3001\u91d1\u5c5e\u3068\u914d\u4f4d\u5b50\u306e\u7d44\u307f\u5408\u308f\u305b\u3084\u932f\u4f53\u306e\u69cb\u9020\u304c\u6975\u3081\u3066\u91cd\u8981\u306b\u306a\u308a\u307e\u3059\u3002\u308f\u305f\u3057\u305f\u3061\u306f\u9069\u5207\u306a\u5206\u5b50\u8a2d\u8a08\u3092\u65bd\u3059\u3053\u3068\u3067\u3001\u6975\u3081\u3066\u9ad8\u3044\u6c34\u7d20\u5316\u6d3b\u6027\u3092\u793a\u3059\u5206\u5b50\u89e6\u5a92\u3092\u958b\u767a\u3059\u308b\u3053\u3068\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002\u56f3\uff12-\uff15\u306b\u793a\u3059\u3088\u3046\u306bRUCY\u3068\u540d\u4ed8\u3051\u3089\u308c\u305f\u3053\u306e\u89e6\u5a92\u306f\u3001\u5148\u307b\u3069\u793a\u3057\u305f\u89e6\u5a92\u3068\u306f\u7570\u306a\u308a\u3001\u7279\u7570\u306a\u30eb\u30c6\u30ca\u30d3\u30b7\u30af\u30ed\u9aa8\u683c\u3092\u3082\u3061\u3001\u9069\u5207\u306a\u6761\u4ef6\u4e0b\u306710\u4e07\u500d\u91cf\u306e\u30a2\u30bb\u30c8\u30d5\u30a7\u30ce\u30f3\uff08\u30b1\u30c8\u30f3\uff09\u3092\u50c5\u304b6\u5206\u3067\u3059\u3079\u3066\u30a2\u30eb\u30b3\u30fc\u30eb\u306b\u5909\u63db\u3067\u304d\u307e\u3059<sup>[B4]<\/sup>\u3002\u305d\u306e\u4ed5\u4e8b\u52b9\u7387\u306f\u6bce\u52063\u4e075\u5343\u56de\u3001\u6bce\u79d2\u3067\u306f583\u56de\u3067\u3001F1\u30de\u30b7\u30f3\u306e\u30a8\u30f3\u30b8\u30f3\u306e\u56de\u8ee2\u901f\u5ea6\u3092\u512a\u306b\u51cc\u99d5\u3057\u307e\u3059\u3002\u30a8\u30ca\u30f3\u30c1\u30aa\u9078\u629e\u6027\u3082\u307b\u307c\u5b8c\u74a7\u3067\u3001\u9769\u65b0\u7684\u306a\u9032\u6b69\u3067\u3042\u308b\u3068\u8003\u3048\u3066\u3044\u307e\u3059\u3002\u3053\u306e\u89e6\u5a92\u3082\u793e\u4f1a\u306b\u5f79\u7acb\u3066\u308b\u305f\u3081\u8a66\u85ac\u8ca9\u58f2\u3092\u958b\u59cb\u3057\u307e\u3057\u305f\u3002<\/p>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter size-full wp-image-495\" src=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/6e8b190971b60a89390f6275696650f9.png\" alt=\"\u30b9\u30e9\u30a4\u30c907\" width=\"720\" height=\"540\" srcset=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/6e8b190971b60a89390f6275696650f9.png 720w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/6e8b190971b60a89390f6275696650f9-300x225.png 300w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/6e8b190971b60a89390f6275696650f9-230x173.png 230w\" sizes=\"(max-width: 720px) 100vw, 720px\" \/><\/p>\n<p>\u3072\u3068\u304f\u3061\u306b\u30b1\u30c8\u30f3\u3068\u3044\u3063\u3066\u3082\u69d8\u3005\u306a\u69cb\u9020\u304c\u3042\u308a\u3001\u4e00\u3064\u306e\u89e6\u5a92\u3067\u305d\u306e\u3059\u3079\u3066\u3092\u4e0d\u6589\u6c34\u7d20\u5316\u3059\u308b\u3053\u3068\u306f\u3067\u304d\u307e\u305b\u3093\u3002\u305d\u3053\u3067\u308f\u305f\u3057\u305f\u3061\u306f\u3001\u7279\u7570\u306a\u69cb\u9020\u3092\u3082\u3064\u30b1\u30c8\u30f3\u306b\u3082\u5bfe\u5fdc\u3067\u304d\u308b\u30c6\u30fc\u30e9\u30fc\u30e1\u30a4\u30c9\u306a\u89e6\u5a92\u958b\u767a\u306b\u6311\u6226\u3057\u307e\u3057\u305f\u3002\u305d\u306e\u6210\u679c\u306e\u4e00\u4f8b\u3092\u56f3\uff12-\uff16\u306b\u793a\u3057\u307e\u3059\u3002\u30ab\u30eb\u30b3\u30f3\u306e\u30a2\u30ea\u30eb\u30a2\u30eb\u30b3\u30fc\u30eb\u3078\u306e\u6c34\u7d20\u5316\u3067\u306f\u3001TolBINAP\u3068DMAPEN\u3092\u914d\u4f4d\u5b50\u306b\u7528\u3044\u308b\u3053\u3068\u3067\u3001\u9175\u7d20\u6cd5\u3092\u542b\u3081\u3001\u521d\u3081\u3066\u9ad8\u7acb\u4f53\u9078\u629e\u7684\u306a\u9084\u5143\u3092\u9054\u6210\u3057\u307e\u3057\u305f<sup>[B5]<\/sup>\u3002<a href=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/2-6.pdf\" target=\"_blank\" rel=\"noopener noreferrer\">\uff08PDF\uff09<\/a><\/p>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter size-full wp-image-496\" src=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/0102562b58277cf46fa1af23c664ffc5.png\" alt=\"\u30b9\u30e9\u30a4\u30c908\" width=\"720\" height=\"540\" srcset=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/0102562b58277cf46fa1af23c664ffc5.png 720w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/0102562b58277cf46fa1af23c664ffc5-300x225.png 300w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/0102562b58277cf46fa1af23c664ffc5-230x173.png 230w\" sizes=\"(max-width: 720px) 100vw, 720px\" \/><\/p>\n<p>\u56f3\uff12-\uff17\u306b\u793a\u3059\u3088\u3046\u306b\u3001XylSkewphos\u3068\u03b1-\u30d4\u30b3\u30ea\u30eb\u30a2\u30df\u30f3\uff08PICA\uff09\u3092\u914d\u4f4d\u5b50\u3068\u3059\u308b\u30eb\u30c6\u30cb\u30a6\u30e0\u932f\u4f53\u306f\u6975\u3081\u3066\u9ad8\u3044\u89e6\u5a92\u6d3b\u6027\u3092\u793a\u3057\u3001\u6df7\u307f\u5408\u3063\u305f\u30d3\u30b7\u30af\u30ed[2.2.2]\u9aa8\u683c\u3092\u3082\u30643-\u30ad\u30cc\u30af\u30ea\u30b8\u30ce\u30f3\u3092\u52b9\u7387\u7684\u306b3-\u30ad\u30cc\u30af\u30ea\u30b8\u30ce\u30fc\u30eb\u306b\u6c34\u7d20\u5316\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059<sup>[B6]<\/sup>\u300210\u4e07\u500d\u91cf\u306e\u30b1\u30c8\u30f3\u30924\u6642\u9593\u4ee5\u5185\u306b\u9084\u5143\u3067\u304d\u307e\u3059\u3002\u5316\u5b66\u7cfb\u4f01\u696d\u3068\u306e\u5171\u540c\u7814\u7a76\u3067\u3001540\u30ad\u30ed\u898f\u6a21\u306e\u53cd\u5fdc\u3082\u9054\u6210\u3057\u3001\u5b9f\u7528\u5316\u306b\u6210\u529f\u3057\u307e\u3057\u305f\u3002\u751f\u6210\u7269\u3067\u3042\u308b\u5149\u5b66\u6d3b\u60273-\u30ad\u30cc\u30af\u30ea\u30b8\u30ce\u30fc\u30eb\u306f\u5c3f\u5931\u7981\u304a\u3088\u3073\u983b\u5c3f\u306a\u3069\u306e\u6cbb\u7642\u85ac\u3068\u3057\u3066\u77e5\u3089\u308c\u308b\u30bd\u30ea\u30d5\u30a7\u30ca\u30b7\u30f3\u306e\u9375\u3068\u306a\u308b\u5408\u6210\u539f\u6599\u3067\u3059\u30022009\u5e74\u5ea6\u4ee5\u964d\u306710\u30c8\u30f3\u4ee5\u4e0a\u88fd\u9020\u3057\u3066\u3044\u307e\u3059\u3002<a href=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/2-7.pdf\" target=\"_blank\" rel=\"noopener noreferrer\">\uff08PDF\uff09<\/a><\/p>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter size-full wp-image-497\" src=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/c6db9b558a62d1c26990297d28cc6901.png\" alt=\"\u30b9\u30e9\u30a4\u30c909\" width=\"720\" height=\"540\" srcset=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/c6db9b558a62d1c26990297d28cc6901.png 720w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/c6db9b558a62d1c26990297d28cc6901-300x225.png 300w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/c6db9b558a62d1c26990297d28cc6901-230x173.png 230w\" sizes=\"(max-width: 720px) 100vw, 720px\" \/><\/p>\n<p>\u3055\u3089\u306b\u8907\u96d1\u306a\u69cb\u9020\u3092\u3082\u30642-(\u30b8\u30d5\u30a7\u30cb\u30eb\u30e1\u30c1\u30eb)-3-\u30ad\u30cc\u30af\u30ea\u30b8\u30ce\u30f3\u306e\u6c34\u7d20\u5316\u306b\u306f\u3001\u56f3\uff12-\uff18\u306b\u793a\u3059BINAP\u3068IPHAN\u3092\u914d\u4f4d\u5b50\u3068\u3059\u308b\u932f\u4f53\u304c\u975e\u5e38\u306b\u512a\u308c\u3066\u3044\u308b\u3053\u3068\u304c\u308f\u304b\u308a\u307e\u3057\u305f<sup>[B7]<\/sup>\u30024\u7a2e\u985e\u53ef\u80fd\u6027\u304c\u3042\u308b\u751f\u6210\u7269\u306e\u3046\u3061\u30011\u7a2e\u985e\u3060\u3051\u304c\u307b\u307c\u5b8c\u74a7\u306a\u7acb\u4f53\u9078\u629e\u6027\u3067\u5f97\u3089\u308c\u307e\u3059\u3002<\/p>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter size-full wp-image-498\" src=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/7d90b81ae27a13938e211e1ed1f9a2dc.png\" alt=\"\u30b9\u30e9\u30a4\u30c910\" width=\"720\" height=\"540\" srcset=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/7d90b81ae27a13938e211e1ed1f9a2dc.png 720w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/7d90b81ae27a13938e211e1ed1f9a2dc-300x225.png 300w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/7d90b81ae27a13938e211e1ed1f9a2dc-230x173.png 230w\" sizes=\"(max-width: 720px) 100vw, 720px\" \/><\/p>\n<p>\u30b1\u30c8\u30f3\u306e\u30b1\u30a4\u7d20\u7b49\u4fa1\u4f53\u3068\u3057\u3066\u6ce8\u76ee\u3055\u308c\u3066\u3044\u308b\u30a2\u30b7\u30eb\u30b7\u30e9\u30f3\u306f\u3001\u53cd\u5fdc\u70b9\u8fd1\u508d\u304c\u7acb\u4f53\u7684\u306b\u304b\u3055\u9ad8\u3044\u3053\u3068\u306b\u52a0\u3048\u3066\u3001\u6c34\u7d20\u5316\u6761\u4ef6\u306b\u4e0d\u5b89\u5b9a\u3067\u3042\u308b\u305f\u3081\u3001\u6709\u52b9\u306a\u4e0d\u6589\u6c34\u7d20\u5316\u89e6\u5a92\u304c\u77e5\u3089\u308c\u3066\u3044\u307e\u305b\u3093\u3067\u3057\u305f\u3002\u308f\u305f\u3057\u305f\u3061\u306f\u3001\u56f3\uff12-\uff19\u306b\u793a\u3059TolBINAP\u3068PICA\u3092\u914d\u4f4d\u5b50\u3068\u3059\u308b\u932f\u4f53\u3092\u89e6\u5a92\u306b\u7528\u3044\u308b\u3053\u3068\u3067\u3001\u4e16\u754c\u306b\u5148\u99c6\u3051\u3066\u30a2\u30b7\u30eb\u30b7\u30e9\u30f3\u985e\u306e\u9ad8\u901f\u304b\u3064\u9ad8\u7acb\u4f53\u9078\u629e\u7684\u6c34\u7d20\u5316\u306e\u958b\u767a\u306b\u6210\u529f\u3057\u307e\u3057\u305f<sup>[B8]<\/sup>\u3002<\/p>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter size-full wp-image-500\" src=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/8da89575c9b3441c9971d7a8cbab1c3e.png\" alt=\"\u30b9\u30e9\u30a4\u30c911\" width=\"720\" height=\"540\" srcset=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/8da89575c9b3441c9971d7a8cbab1c3e.png 720w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/8da89575c9b3441c9971d7a8cbab1c3e-300x225.png 300w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/8da89575c9b3441c9971d7a8cbab1c3e-230x173.png 230w\" sizes=\"(max-width: 720px) 100vw, 720px\" 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href=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/2-10.pdf\" target=\"_blank\" rel=\"noopener noreferrer\">\uff08PDF\uff09<\/a><\/p>\n<p><img decoding=\"async\" loading=\"lazy\" class=\"aligncenter size-full wp-image-501\" src=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/df292ad6b3fa1d41cf98b96a04be1b8e.png\" alt=\"\u30b9\u30e9\u30a4\u30c912\" width=\"720\" height=\"540\" srcset=\"https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/df292ad6b3fa1d41cf98b96a04be1b8e.png 720w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/df292ad6b3fa1d41cf98b96a04be1b8e-300x225.png 300w, https:\/\/c-mng.cwh.hokudai.ac.jp\/orgsynth.eng\/Root\/wp-content\/uploads\/2016\/01\/df292ad6b3fa1d41cf98b96a04be1b8e-230x173.png 230w\" sizes=\"(max-width: 720px) 100vw, 720px\" 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